Hückelovo pravidlo
Aby byla daná latka aromatická, musí být molekula planární, monocyklická, mít dokonale konjugovaný systém vazeb a splňovat právě onu Hückelovu podmínku. Ta říká, že počet pí-elektronů ve sloučenině musí být roven číslu 4n+2, tedy matematicky P= 4n+2, kde P je počet pí-elektronů a n je libovolné celé nezáporné číslo.
Ovšem proč zrovna 4n+2??? Co je na této kombinaci tak speciálního? Proč tedy zrovna 2, 6, 10, 14... pí-elektronů vede k aromaticitě a poměrně vysoké stabilitě, zatímco ostatní kombinace vedou k větší či menší nestabilitě. Odpověď se skrývá v "tajemné" teorii molekulových orbitalů (MO).
Pokud se totiž spočítají energetické hladiny molekulových orbitalů pro cyklické konjugované molekuly, ukáže se, že vždy existuje jeden nejníže ležící MO, nad kterým existují MO v degenerovaných párech. Tedy, při zaplňováníí MO je vždy potřeba dvou elektronů na zaplnění nejníže ležícího osamoceného MO a poté vždy čtyř elektronů na zaplnění každé z n následujících energetických hladin - dohromady tedy 2 + 4n. Každý jiný počet zanechá energetickou hladinu částečně nezaplněnou a tedy méně stabilní.
OBR: Molekulové orbitaly pro benzen:
1. Šipka vlevo ukazuje růst energie systému
2. Šest nedegenerovaných 2p atomových orbitalů (AO) šesti atomů uhlíku v cyklu benzenu s jedním elektronem v každém z nich
3. Při konjugaci a vzniku molekulových orbitalů vznikají tři vazebné MO o nižší energii než měly puvodní AO (dva jsou degenerované) a tři protivazebné MO o vyšší energii než měly původní AO (dva jsou opět degenerované)
4. Vazebné MO jsou zaplněny elektrony - je vidět, proč jich musí být právě 4n + 2 - tak dojde k zaplnění všech vazebných MO, kdyby jich byl jiný počet, některá místa by byla zbytečně volná.
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-Custom of father-son household company
2. Shop Ambiance as well as Expert services
-Aged school barber shop beautification - marbled flooring, natural leather recliners, very hot lather devices
-Focus on men's hair styling services - , short haircuts, lightens, flat tops, styling
-Conventional hot towel shaves your face along with direct cutter
-Manicures along with foot soaks also made available
https://www.yelp.com/biz/dinos-barbershop-san-diego-2
3. Barbershop Team
-Dean jerrod still slicing hair close to kid Mario
-Competent stylists Lenny, Vincenzo as well as Paul
-Around A hundred years of combined barbering encounter
-Comfortable as well as fun personalities - full of life store badinage, persiflage
4. Clientele
-Many generation trustworthy consumer foundation
-Dads delivering sons for first haircuts
-No consultations required - stroll-ins encouraged
5. Providing Back to be able to the Local community
-Annual school supply drives regarding youngsters
-Sponsor neighborhood Little League football teams
-Assistance numerous aid organizations along with leads to
Bottom line:
-Overview of Dino's classic barber expert services as well as values
-Tackle, a long time, mobile phone number along with internet site listed
Permit me recognize when you would such as me to be able to expand upon just about any particular section throughout more aspect.
The Cut Higher than the actual Rest - Dino's Barbershop
(Tylerfub, 16. 11. 2023 18:11)
-Review of Dino's Barber shop, any vintage barber helping the particular community for above 25 years.
Primary Areas:
1. Background and Ownership
-Started in 1980 by Dino Rossi within Smallville, USA
-Approved along to be able to his son Mario Rossi within 2010
-Tradition of father-son family business
2. Go shopping Feeling and Expert services
-Aged school barbershop decor - marble floorings, buckskin car seats, very hot suds machines
-Focus in mens haircutting expert services - , short haircuts, fades, flat tops, styling
-Traditional hot towel shaves your face together with directly razor
-Manicures and pedicures as well as pedicures likewise provided
https://www.yelp.com/biz/dinos-barbershop-san-diego-2
3. Barber shop Staff
-Dino nonetheless slicing hair alongside son Laptop computer
-Experienced stylists Luigi, Vincent along with Stan
-Over 100 many years of combined barber encounter
-Cozy as well as fun individuality - full of life shop chatter
4. Customers
-Multigenerational trustworthy customer foundation
-Fathers bringing sons with regard to very first hair cuts
-Simply no consultations required - go-ins greeted
5. Giving Again to be able to the particular Community
-Annual school present hard disks regarding kids
-Sponsor nearby Small Category football teams
-Help different non profit organizations as well as brings about
Realization:
-Recap of Dino's traditional barber shop expert services and beliefs
-Deal with, several hours, mobile phone number and site listed
Permit everyone recognize when a person would such as myself in order to expand upon any specific area in more detail.
One Trim Above the Relaxation - Dino's Barber shop
(Tylerfub, 16. 11. 2023 17:00)
-Introduction of Dino's Barber shop, any vintage barber providing the community for above 40 many years.
Main Portions:
1. History along with Control
-Started within 1980 simply by Dean jerrod Rossi throughout Smalltown, USA
-Transferred along in order to his kid Laptop computer Rossi within 2010
-Tradition of pops-son loved ones small business
2. Shop Atmosphere as well as Services
-Aged school barbershop beautification - marble floors, natural leather chairs, hot suds devices
-Focus on to locate haircutting expert services - buzzcuts, lightens, flat surfaces, styling
-Classic popular soft towel shaves your face with direct razor
-Manicures and pedicures as well as foot soaks likewise provided
https://www.yelp.com/biz/dinos-barbershop-san-diego-2
3. Barbershop Group
-Daniel nonetheless cutting hair next to boy Laptop computer
-Experienced barbers Lenny, Vincenzo along with Stan
-Over A hundred decades of put together hair styling encounter
-Comfortable as well as fun figures - full of life store banter
4. Patrons
-Many generation loyal customer base
-Fathers bringing youngsters regarding very first haircuts
-Simply no appointments necessary - stroll-ins encouraged
5. Giving Returning to the actual Neighborhood
-Twelve-monthly university supply turns regarding children
-Host nearby Tiny League baseball teams
-Assistance different charities along with leads to
Realization:
-Summary of Dino's classic barbershop expert services along with ideals
-Tackle, several hours, phone quantity along with site shown
Let me understand if an individual might like me to broaden on any particular portion in a lot more detail.
The Cut Higher than the actual Sleep - Dino's Barber
(Tylerfub, 16. 11. 2023 13:37)
-Review of Dino's Barber shop, a traditional barber shop providing the actual local community with regard to over 25 decades.
Primary Portions:
1. Historical past along with Control
-Started in 1980s through Daniel Rossi throughout Tiny metropolis, U. S. A.
-Passed down in order to their kid Morrison a pardon Rossi throughout 2010
-Tradition of dad-kid loved ones business
2. Store Atmosphere as well as Expert services
-Aged university barbershop decor - marble floors, leather chairs, popular suds machines
-Focus upon to locate hairstyling expert services - buzzcuts, fades, apartment covers, design
-Classic popular towel shaves your face along with straight razor
-Manicures and pedicures and pedicures likewise provided
https://www.yelp.com/biz/dinos-barbershop-san-diego-2
3. Barber shop Staff
-Dino still trimming head of hair next to son Mario
-Experienced barbers Lenny, Vincent and Stan
-Above 100 years of put together barber knowledge
-Warm and exciting individuality - full of life store badinage, persiflage
4. Patrons
-Many generation loyal client foundation
-Fathers bringing kids with regard to initial hairstyles
-Zero prearranged appointments necessary - go-ins encouraged
5. Giving Again in order to the particular Neighborhood
-Yearly school provide hard disks regarding children
-Host neighborhood Little Group hockey groups
-Help different charities and causes
Bottom line:
-Summary of Dino's classic barbershop providers and beliefs
-Address, hours, phone number and site shown
Let myself recognize if a person would similar to everyone to be able to expand about any certain area throughout a lot more aspect.
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Struggling regarding The law along with Martinicchio Criminal Security Group
(Warrenbrack, 20. 11. 2023 10:58)